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Sei composite multiparticle (#4693)
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aabills authored Jan 3, 2025
1 parent f79cd26 commit a5616c9
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1 change: 1 addition & 0 deletions CHANGELOG.md
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Expand Up @@ -2,6 +2,7 @@

## Features

- Enabled using SEI models with particle size distributions. ([#4693](https://github.com/pybamm-team/PyBaMM/pull/4693))
- Added symbolic mesh which allows for using InputParameters for geometric parameters ([#4665](https://github.com/pybamm-team/PyBaMM/pull/4665))
- Enhanced the `search` method to accept multiple search terms in the form of a string or a list. ([#4650](https://github.com/pybamm-team/PyBaMM/pull/4650))
- Made composite electrode model compatible with particle size distribution ([#4687](https://github.com/pybamm-team/PyBaMM/pull/4687))
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11 changes: 6 additions & 5 deletions src/pybamm/models/full_battery_models/base_battery_model.py
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Expand Up @@ -526,10 +526,15 @@ def __init__(self, extra_options):
# Options not yet compatible with particle-size distributions
if options["particle size"] == "distribution":
if options["lithium plating porosity change"] != "false":
raise NotImplementedError(
raise pybamm.OptionError(
"Lithium plating porosity change not yet supported for particle-size"
" distributions."
)
if options["SEI porosity change"] == "true":
raise NotImplementedError(
"SEI porosity change submodels do not yet support particle-size "
"distributions."
)
if options["heat of mixing"] != "false":
raise NotImplementedError(
"Heat of mixing submodels do not yet support particle-size "
Expand All @@ -550,10 +555,6 @@ def __init__(self, extra_options):
"Particle shape must be 'spherical' for particle-size distribution"
" submodels."
)
if options["SEI"] != "none":
raise NotImplementedError(
"SEI submodels do not yet support particle-size distributions."
)
if options["stress-induced diffusion"] == "true":
raise NotImplementedError(
"stress-induced diffusion cannot yet be included in "
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Expand Up @@ -151,6 +151,10 @@ def get_coupled_variables(self, variables):
j_tot.print_name = "j_tot"

eta_sei = -j_tot * L_sei * R_sei
if self.size_distribution and eta_r.domains["secondary"] != [
f"{domain} electrode"
]:
eta_sei = pybamm.x_average(eta_sei)
else:
eta_sei = pybamm.Scalar(0)
eta_r += eta_sei
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Expand Up @@ -313,6 +313,13 @@ def test_options(self):
"plating porosity change"
}
)
with pytest.raises(pybamm.OptionError, match="distributions"):
pybamm.BaseBatteryModel(
{
"particle size": "distribution",
"lithium plating porosity change": "true",
}
)

# contact resistance
with pytest.raises(pybamm.OptionError, match="contact resistance"):
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Expand Up @@ -98,7 +98,7 @@ def test_reversible_plating_with_porosity_not_implemented(self):
"lithium plating": "reversible",
"lithium plating porosity change": "true",
}
with pytest.raises(NotImplementedError):
with pytest.raises(pybamm.OptionError, match="distributions"):
pybamm.lithium_ion.MPM(options)

def test_stress_induced_diffusion_not_implemented(self):
Expand Down Expand Up @@ -159,25 +159,25 @@ def external_circuit_function(variables):


class TestMPMWithSEI:
def test_reaction_limited_not_implemented(self):
def test_reaction_limited(self):
options = {"SEI": "reaction limited"}
with pytest.raises(NotImplementedError):
pybamm.lithium_ion.MPM(options)
model = pybamm.lithium_ion.MPM(options)
model.check_well_posedness()

def test_solvent_diffusion_limited_not_implemented(self):
def test_solvent_diffusion_limited(self):
options = {"SEI": "solvent-diffusion limited"}
with pytest.raises(NotImplementedError):
pybamm.lithium_ion.MPM(options)
model = pybamm.lithium_ion.MPM(options)
model.check_well_posedness()

def test_electron_migration_limited_not_implemented(self):
def test_electron_migration_limited(self):
options = {"SEI": "electron-migration limited"}
with pytest.raises(NotImplementedError):
pybamm.lithium_ion.MPM(options)
model = pybamm.lithium_ion.MPM(options)
model.check_well_posedness()

def test_interstitial_diffusion_limited_not_implemented(self):
def test_interstitial_diffusion_limited(self):
options = {"SEI": "interstitial-diffusion limited"}
with pytest.raises(NotImplementedError):
pybamm.lithium_ion.MPM(options)
model = pybamm.lithium_ion.MPM(options)
model.check_well_posedness()

def test_ec_reaction_limited_not_implemented(self):
options = {
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