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发展高性能 NIR-II 荧光分子染料对推动 NIR-II 能易于调控的特点引起了研究者们的兴趣。然而,目前将其应用于 NIR-II 荧光成像的报道较少,且对其分子结构与染料在水中的光学性能间的关系研究较少。 | ||
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本工作设计并合成了一系列 A-D-A 型稠环受体分子,进一步用两亲性聚合物包裹制备了水溶性 NIR-II 纳米荧光染料,通过对受体单元上卤素原子取代基 的数量和类型、氰基引入进行调控,结合理论计算,研究A 单元结构与染料在水中光学性能(摩尔消光系数、吸收与发射波长、QY)间的关系。 |
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